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Appendix I to Part 150--Exceptions to the Chart
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(a). The binary combinations listed below have been tested as
prescribed in Appendix III and found not to be dangerously reactive.
These combinations are exceptions to the Compatibility Chart (Figure 1)
and may be stowed in adjacent tanks.
------------------------------------------------------------------------
Member of reactive group Compatible with
------------------------------------------------------------------------
Acetone (18).............................. Diethylenetriamine (7)
Acetone cyanohydrin (0)................... Acetic acid (4)
Acrylonitrile (15)........................ Triethanolamine (8)
1,3-Butylene glycol (20).................. Morpholine (7)
1,4-Butylene glycol (20).................. Ethylamine (7)
Triethanolamine (8)
gamma-Butyrolactone (0)................... N-Methyl-2-pyrrolidone (9)
Caustic potash, 50% or less (5)........... Isobutyl alcohol (20)
Ethyl alcohol (20)
Ethylene glycol (20)
Isopropyl alcohol (20)
Methyl alcohol (20)
iso-Octyl alcohol (20)
Caustic soda, 50% or less (5)............. Butyl alcohol (20)
tert-Butyl alcohol, Methanol
mixtures
Decyl alcohol (20)
iso-Decyl alcohol (20)
Diacetone alcohol (20)
Diethylene glycol (40)
Ethyl alcohol (20)
Ethyl alcohol (40%, whiskey)
(20)
Ethylene glycol (20)
Ethylene glycol, Diethylene
glycol mixture (20)
Ethyl hexanol (Octyl
alcohol) (20)
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Methyl alcohol (20)
Nonyl alcohol (20)
iso-Nonyl alcohol (20)
Propyl alcohol (20)
Propylene glycol (20)
Sodium chlorate (0)
iso-Tridecanol (20)
Dodecyl and Tetradecylamine mixture (7)... Tall oil, fatty acid (34)
Ethylenediamine (7)....................... Butyl alcohol (20)
tert-Butyl alcohol (20)
Butylene glycol (20)
Creosote (21)
Diethylene glycol (40)
Ethyl alcohol (20)
Ethylene glycol (20)
Ethyl hexanol (20)
Glycerine (20)
Isononyl alcohol (20)
Isophorone (18)
Methyl butyl ketone (18)
Methyl iso-butyl ketone (18)
Methyl ethyl ketone (18)
Propyl alcohol (20)
Propylene glycol (20)
Oleum (0)................................. Hexane (31)
Dichloromethane (36)
Perchloroethylene (36)
1,2-Propylene glycol (20)................. Diethylenetriamine (7)
Polyethylene polyamines (7)
Triethylenetetramine (7)
Sodium dichromate, 70% (0)................ Methyl alcohol (20)
Sodium hydrosulfide solution (5).......... iso-Propyl alcohol (20)
Sulfuric acid (2)......................... Coconut oil (34)
Coconut oil acid (34)
Palm oil (34)
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Tallow (34)
Sulfuric acid, 98% or less (2)............ Choice white grease tallow (34)
(b). The binary combinations listed below have been determined to be dangerously reactive, based on either data obtained in the literature or on laboratory testing which has been carried out in accordance with procedures prescribed in Appendix III. These combinations are exceptions to the Compatibility Chart (Figure 1) and may not be stowed in adjacent tanks.
Acetone cyanohydrin (0) is not compatible with Groups 1-12, 16, 17 and 22.
Acrolein (19) is not compatible with Group 1, Non-Oxidizing Mineral Acids.
Acrylic acid (4) is not compatible with Group 9, Aromatic Amines.
Acrylonitrile (15) is not compatible with Group 5 (Caustics).
Alkylbenzenesulfonic acid (0) is not compatible with Groups 1-3, 5-9, 15, 16, 18, 19, 30, 34, 37, and strong oxidizers.
Allyl alcohol (15) is not compatible with Group 12, Isocyanates.
Alkyl(C7-C9) nitrates (34) is not compatible with Group 1, Non-oxidizing Mineral Acids.
Aluminum sulfate solution (43) is not compatible with Groups 5-11.
Ammonium bisulfite solution (43) is not compatible with Groups 1, 3, 4, and 5.
Benzenesulfonyl chloride (0) is not compatible with Groups 5-7, and 43.
1,4-Butylene glycol (20) is not compatible with Caustic soda solution, 50% or less (5).
gamma-Butyrolactone (0) is not compatible with Groups 1-9.
Caustic soda solution, 50% or less (5) is not compatible with 1,4- Butylene glycol (20).
Crotonaldehyde (19) is not compatible with Group 1, Non-Oxidizing Mineral Acids.
Cyclohexanone, Cyclohexanol mixture (18) is not compatible with Group 12, Isocyanates.
2,4-Dichlorophenoxyacetic acid, Triisopropanolamine salt solution (43) is not compatible with Group 3, Nitric Acid.
2,4-Dichlorophenoxyacetic acid, Dimethylamine salt solution (0) is not compatible with Groups 1-5, 11, 12, and 16.
Dimethyl hydrogen phosphite (34) is not compatible with Groups 1 and 4.
Dimethyl naphthalene sulfonic acid, sodium salt solution (34) is not compatible with Group 12, Formaldehyde, and strong oxidizing agents.
Dodecylbenzenesulfonic acid (0) is not compatible with oxidizing agents and Groups 1, 2, 3, 5, 6, 7, 8, 9, 15, 16, 18, 19, 30, 34, and 37.
Ethylenediamine (7) is not compatible with Ethylene dichloride (36).
Ethylene dichloride (36) is not compatible with Ethylenediamine (7).
Ethylidene norbornene (30) is not compatible with Groups 1-3 and 5-8.
2-Ethyl-3-propylacrolein (19) is not compatible with Group 1, Non-Oxidizing Mineral Acids.
Ferric hydroxyethylethylenediamine triacetic acid, Sodium salt solution (43) is not compatible with Group 3, Nitric acid.
Fish oil (34) is not compatible with Sulfuric acid (2).
Formaldehyde (over 50%) in Methyl alcohol (over 30%) (19) is not compatible with Group 12, Isocyanates.
Formic acid (4) is not compatible with Furfural alcohol (20).
Furfuryl alcohol (20) is not compatible with Group 1, Non-Oxidizing Mineral Acids and Formic acid (4).
2-Hydroxyethyl acrylate is not compatible with Groups 2, 3, 5-8 and 12.
Isophorone (18) is not compatible with Group 8, Alkanolamines.
Magnesium chloride solution (0) is not compatible with Groups 2, 3, 5, 6 and 12.
Mesityl oxide (18) is not compatible with Group 8, Alkanolamines.
Methacrylonitrile (15) is not compatible with Group 5 (Caustics).
Methyl tert-butyl ether (41) is not compatible with Group 1, Non-oxidizing Mineral Acids.
Naphtha, cracking fraction (33) is not compatible with strong acids, caustics or oxidizing agents.
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o-Nitrophenol (0) is not compatible with Groups 2, 3, and 5-10.
Octyl nitrates (all isomers), see Alkyl(C7-C9) nitrates.
Oleum (0) is not compatible with Sulfuric acid (2) and 1,1,1-Trichloroethane (36).
Phthalate based polyester polyol (0) is not compatible with group 2, 3, 5, 7 and 12.
Pentene, Miscellaneous hydrocarbon mixtures (30) are not compatible with strong acids or oxidizing agents.
Polyglycerine, Sodium salts solution (20) is not compatible with Groups 1, 4, 11, 16, 17, 19, 21 and 22.
Sodium acetate, Glycol, Water mixture (1% or less Sodium hydroxide) (34) is not compatible with Group 12 (Isocyanates).
Sodium chlorate solution (50% or less) (0) is not compatible with Groups 1-3, 5, 7, 8, 10, 12, 13, 17 and 20.
Sodium dichromate solution (70% or less) (0) is not compatible with Groups 1-3, 5, 7, 8, 10, 12, 13, 17 and 20.
Sodium dimethyl naphthalene sulfonate solution (34) is not compatible with Group 12, Formaldehyde and strong oxidizing agents.
Sodium hydrogen sulfide, Sodium carbonate solution (0) is not compatible with Groups 6 (Ammonia) and 7 (Aliphatic amines).
Sodium hydrosulfide (5) is not compatible with Groups 6 (Ammonia) and 7 (Aliphatic amines).
Sodium hydrosulfide, Ammonium sulfide solution (5) is not compatible with Groups 6 (Ammonia) and 7 (Aliphatic amines).
Sodium polyacrylate solution (43) is not compatible with Group 3, Nitric Acid.
Sodium salt of Ferric hydroxyethylethylenediamine triacetic acid solution (43) is not compatible with Group 3, Nitric acid.
Sodium silicate solution (43) is not compatible with Group 3, Nitric Acid.
Sodium sulfide, hydrosulfide solution (0) is not compatible with Groups 6 (Ammonia) and 7 (Aliphatic amines).
Sodium thiocyanate (56% or less) (0) is not compatible with Groups 1-4.
Sulfonated polyacrylate solution (43) is not compatible with Group 5
(Caustics).
Sulfuric acid (2) is not compatible with Fish oil (34), or Oleum (0).
Tallow fatty acid (34) is not compatible with Group 5, Caustics.
1,1,1-Trichloroethane (36) is not compatible with Oleum (0).
Trichloroethylene (36) is not compatible with Group 5, Caustics.
Triethyl phosphite (34) is not compatible with Groups 1, and 4.
Trimethyl phosphite (34) is not compatible with Groups 1 and 4.
1,3,5-Trioxane (41) is not compatible with Group 1 (non-oxidizing mineral acids) and Group 4 (Organic acids).
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